Reaction Mechanisms (GATE CY) — Study Resources & PYQs
Reaction Mechanisms: Basic mechanistic concepts and energy profile diagrams - kinetics versus thermodynamic control, Hammond’s postulate and Curtin-Hammett principle. Methods of determining reaction mechanisms through kinetics, identification of products, intermediates and isotopic labelling. Solvent effects in substitution and elimination reactions. Linear free-energy relationship – Hammett and Taft equations.